The safety performance of power batteries is influenced by a wide range of factors throughout their entire lifecycle, from the selection of materials to the end of use. These factors include the intrinsic properties of the cell materials, the manufacturing process, the design and operation of the Battery Management System (BMS), and the integration of the battery into larger systems. Due to the complexity of these elements, it's nearly impossible to eliminate all potential risks. Manufacturing errors, as well as various forms of abuse during use, are inevitable in real-world scenarios. Therefore, designing effective thermal runaway prevention strategies becomes crucial for ensuring the reliability and safety of lithium-ion batteries.
This paper explores the key factors that influence the safety of lithium-ion power batteries, aiming to provide a solid foundation for their safe application in high-energy and high-power systems. The importance of material selection, manufacturing precision, BMS functionality, and system integration cannot be overstated. Each stage of the battery’s life cycle plays a critical role in determining its overall safety profile.
Lithium-ion batteries have become the dominant technology in energy storage due to their high energy density, long cycle life, and relatively low maintenance requirements. They are widely used in portable electronics, electric vehicles, and large-scale energy storage systems. However, despite their general safety, incidents such as fires and explosions have been reported, raising concerns about their reliability. Notable examples include issues with Boeing 737 and 787 aircraft batteries, as well as incidents involving electric vehicles like BYD and Tesla Model S. These events highlight the ongoing challenges in ensuring the safety of lithium-ion batteries, especially under extreme conditions.
Thermal runaway remains one of the most critical safety concerns, as it can lead to catastrophic failures. It is not only a major cause of safety issues but also a limiting factor in achieving higher energy densities and power outputs. Understanding and mitigating the causes of thermal runaway is essential for the continued development and deployment of lithium-ion batteries in demanding applications.
Material selection plays a fundamental role in determining the safety of a battery. For example, cathode materials such as LiFePO4 offer good thermal stability but at the cost of lower energy density, while ternary materials like NMC provide higher energy but face safety challenges. Similarly, anode materials like Li4Ti5O2 and Ti0.9Nb0.1Nb2O7 demonstrate improved safety during fast charging, thanks to their favorable electrochemical properties. Electrolytes and separators also significantly impact safety, with solid electrolytes and advanced separators offering better protection against internal short circuits and thermal events.
During the manufacturing process, even minor defects—such as welding issues, dust contamination, or improper slurry mixing—can lead to internal resistance increases or short circuits, posing serious safety risks. The formation of the SEI film on the anode is another critical step, as it directly affects the battery’s stability and lifespan.
In terms of system integration, the BMS plays a vital role in monitoring and managing battery performance, ensuring safe operation under varying conditions. Advanced BMS features, such as thermal management and high-voltage monitoring, help prevent overheating and other failure modes. Additionally, the design of the battery pack itself must account for potential thermal runaway scenarios, using fireproofing materials, cooling systems, and safety valves to minimize the risk of propagation.
Battery abuse, including overcharging, overheating, mechanical damage, and internal short circuits, further complicates the safety landscape. These conditions can trigger chain reactions that lead to thermal runaway, making it essential to implement robust safeguards and user education.
In conclusion, the safety of lithium-ion power batteries is a multifaceted challenge that spans material science, manufacturing, system design, and real-world usage. While significant progress has been made, there is still much work to be done. By combining theoretical research with practical innovation, the future of high-energy and high-power lithium-ion batteries can be both safer and more efficient.
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